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There is not any single exact relationship between coherence bandwidth and rms delay spread, and equations (1.34) and (1.35) are only approximate equations [1 6,7 10]. Doppler Spread and Coherence Time. To obtain information about the time varying nature of the channel caused by movements, from either the transmitter/ receiver or scatterers located around them, new parameters, such as the Doppler spread and the coherence time, are usually introduced to describe the time variation phenomena of the channel in a small-scale region. The Doppler spread BD is de ned as a range of frequencies over which the received Doppler spectrum is essentially nonzero. It shows the spectral spreading caused by the time rate of change of the mobile radio channel due to the relative motions of vehicles (and scatterers around them) with respect to the base station. According to [1 4,7 10], the Doppler spread BD depends on the Doppler shift fD and on the angle a between the direction of motion of any vehicle and the direction of arrival of the re ected and/or scattered waves (see Fig. 1.3). If we deal with the complex baseband signal presentation, then we can introduce the following criterion: If the baseband signal bandwidth is greater than the Doppler spread BD , the effects of Doppler shift are negligible at the receiver. Coherence time Tc is the time domain dual of Doppler spread, and it is used to characterize the time varying nature of the frequency dispersiveness of the channel in time coordinates. The relationship between these two-channel characteristics is: Tc % 1 l fm v 1:36

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where N x is the mole fraction (or the number-fraction) of molecules of size Mx . The most common methods for measuring M n are membrane osmometry and vapor pressure osmometry since reasonably reliable commercial instruments are available for those methods. Vapor pressure osmometry, which measures vapor pressure indirectly by measuring the change in temperature of a polymer solution on dilution by solvent vapor, is generally useful for polymers with M n below 10,000 15,000. Above that molecular weight limit, the quantity being measured becomes too small to detect by the available instruments. Membrane osmometry is limited to polymers with M n above about 20,000 30,000 and below 500,000. The lower limit is a consequence of the partial permeability of available membranes to smaller-sized polymer molecules. Above molecular weights of 500,000, the osmotic pressure of a polymer solution becomes too small to measure accurately. End-group analysis is also useful for measurements of M n for certain polymers. For example, the carboxyl end groups of a polyester can be analyzed by titration with base and carbon carbon double bond end groups can be analyzed by 1 H NMR. Accurate end-group analysis becomes dif cult for polymers with M n values above 20,000 30,000. 2. Light scattering by polymer solutions, unlike coligative properties, is greater for larger-sized molecules than for smaller-sized molecules. The average molecular weight obtained from light-scattering measurements is the weight-average molecular weight M w de ned as

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We can also de ne the coherence time according to [1 4,7 10] as the time duration over which two multipath components of receiving signal have a strong potential for amplitude correlation. One can also de ne the coherence time as the time over which the correlation function of two various signals in the time domain is above 0.5 (or 50%). Then according to [7,10] we get Tc % 9 9l l 0:18 16pfm 16pv v 1:37

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