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The same products are formed with sodium perborate, a cheap industrial chemical when used in AC20 + H2S04.484 The oxidation of alkenes with H20 2 in the presence of oxide catalysts (W03,485 H2W04,486 Se02487,488) is believed to involve the corresponding inorganic peroxy acids as the oxidizing agent and an epoxide intermediate. W0 3, the most efficient reagent, is used in aqueous medium (for oxidation of water insoluble alkenes), or in acetic acid. 485 Oxidations with Se02 are carried out in alcohols.488 Polymer-bound phenylseleninic acid catalyzes the oxidation of cyclohexene with H20 2 to trans-l,2cyclohexanediol in excellent yield. 489 Oxidation with lead tetraacetate is a far less selective process. 490 ,491 Studied mainly in the oxidation of cycloalkenes, it gives stereoisomeric 1,2-diol diacetates, but side reactions (allylic acetoxylation, skeletal rearrangement) often occur. A change in reaction conditions in the oxidation of cyclopentadiene allows the synthesis of different isomeric mono- and diesters. 492 The iodine-silver carboxylate reagent combination modified by Woodward48o was originally used by Prevost to oxidize alkenes to trans-l,2-diesters. 493 Thallium(l) acetate, mentioned above, as a reagent for syn dihydroxylation can also be used for the synthesis of trans-l ,2-diols. If the reaction is carried out in glacial acetic acid, the intermediate 1,3-dioxolan-2-ylium ion 64 formed from the iodoacetate undergoes ring opening by attack of the acetate ion to yield the trans diacetate482 (Scheme 9.10). In contrast, an aqueous workup affords orthoacetate intermediate, which rearranges to give the cis monoacetate.

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N Patterns: Allows changes to the background color and borders of the title N Font: Allows changes to the font, size, color, and attributes N Alignment: Allows changes to the vertical and horizontal alignment and

1. If the application server that s hosting BlazeDS is currently running, shut it down. 2. Make backup copies of the files in the BlazeDS WEB-INF/flex folder. 3. Copy all of the file and folders from the blazedsfiles folder to the BlazeDS context root folder. If you re using the turnkey distribution in Windows with the recommended installation location, copy the files to:

You can find out how many TOs of each table appear in the Relationships Graph by counting them in the Occurrences in Graph column on the Tables tab of the Manage Database dialog. If you have numerous occurrences, you may need to enlarge the dialog to see them all. Alternatively, you can select one of the Table Occurrences in the Relationships Graph and type +U or Ctrl+U to select all TOs with the same source table and then count the selected TOs.

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